Detection and remediation of organophosphorus compounds by oximate containing organogels† †Electronic supplementary information (ESI) available: This includes experimental details and NMR data. See DOI: 10.1039/c5sc01864a Click here for additional data file.
نویسندگان
چکیده
A series of supramolecular diamide organogels containing a reactive compound for the remediation of organophosphorus (OP) species, in particular OP chemical warfare agents (CWAs), has been prepared in DMSO. The organogels have been found to absorb, encapsulate and decontaminate various OP CWA simulants in situ. At high simulant concentrations the gels also undergo a gel–sol transition releasing high local concentrations of remediation agent.
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Enhanced intersystem crossing in core-twisted aromatics† †Electronic supplementary information (ESI) available: Includes details of the synthesis, structural information for all of the compounds (NMR, elemental analysis and mass spectra) and experimental details for the photophysical studies. CCDC 1402604 and 1402605. For ESI and crystallographic data in CIF or other electronic formats see DOI: 10.1039/c6sc05126j Click here for additional data file. Click here for additional data file.
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Detection and remediation of organophosphorus compounds by oximate containing organogels.
A series of supramolecular diamide organogels containing a reactive compound for the remediation of organophosphorus (OP) species, in particular OP chemical warfare agents (CWAs), has been prepared in DMSO. The organogels have been found to absorb, encapsulate and decontaminate various OP CWA simulants in situ. At high simulant concentrations the gels also undergo a gel-sol transition releasing...
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عنوان ژورنال:
دوره 6 شماره
صفحات -
تاریخ انتشار 2015